After seeing several talks on
electrospinning of polymers, Saul Griffith and I decided to try electrospinning
a nanoparticle colloid of metal to form very fine metal wires. Electrospinning
is technique in which a polymer solution is pumped through a capillary and
exposed to an electric field. The droplet at the end of the capillary
deforms into a conical shape, known as a Taylor cone. If the field
exceeds the critical value to overcome surface tension, the apex of the cone
ejects a jet of material that, depending on viscosity either breaks
into droplets (electrospraying) or forms a continuous stream. Despite
a plethora of patents on electrospinning, there is no work on metals, only
polymers, biopolymers, and some conductive polymers.
Schematic of electrospinning
I believe this is an exciting project, not only because
it is a new space, but because electrospinning of nanoparticles could be
a commericially viable manufacturing technique to make lots of interesting
materials - high surface area to volume catalysts, filters, textiles with
very high conductivity, and the like.
This technique could easily transition to mass-production
manufacture of nano-scale filaments. A fabric woven of these filaments
could display unsual and desirable properties due to the extremely small
size of the filaments. We hope to examine these and other potentially
useful applications during our further studies.
Experimental apparatus
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SEM image of gold wires on a silicon wafer
We chose a solution of gold nanoparticles in a heavy
organic solvent and with a field of approximately 1 kV / cm were able to
create the gold wires shown in the SEM images above and below. Many
of the wires produced are 1 um in diameter, and there remain quite a few
unexplored parameters that could push that diameter even smaller, which
is the focus of current work.
SEM image of gold wires
on a glass slide
The Taylor cone at the end
of the capillary is just visible in this image
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